Canadian Journal of Chemistry

Aryl radicals from hexazadienes and tetrazenes

D Mackay, DD McIntyre

文献索引：Mackay, Donald; McIntyre, Deane Douglas Canadian Journal of Chemistry, 1982 , vol. 60, p. 990 - 999

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被引用次数: 0

摘要

Aryl radicals are produced from both ends of the hexazadienes 1 and 2 and from the tetrazene 3, either thermally or photolytically. They attack aromatic compounds in the nucleus, the yield of biaryl being in the range 40-70%, though it can be made nearly quantitative by using m-dinitrobenzene as an additive. The aryl radicals also oxidize 2- propanol to acetone, the reduction products being the halogenobenzene and 1, 2- ...