Canadian Journal of Chemistry

Aryl radicals from hexazadienes and tetrazenes

D Mackay, DD McIntyre

Index: Mackay, Donald; McIntyre, Deane Douglas Canadian Journal of Chemistry, 1982 , vol. 60, p. 990 - 999

Full Text: HTML

Citation Number: 0

Abstract

Aryl radicals are produced from both ends of the hexazadienes 1 and 2 and from the tetrazene 3, either thermally or photolytically. They attack aromatic compounds in the nucleus, the yield of biaryl being in the range 40-70%, though it can be made nearly quantitative by using m-dinitrobenzene as an additive. The aryl radicals also oxidize 2- propanol to acetone, the reduction products being the halogenobenzene and 1, 2- ...

 Related Synthetic Route
N/A Structure

10312-71-7

N/A

Toluene Structure

108-88-3

Toluene

~%

4-CHLORO-4?-METHYLBIPHENYL Structure

19482-11-2

4-CHLORO-4?-MET...

1-chloro-4-(2-methylphenyl)benzene Structure

89346-57-6

1-chloro-4-(2-m...

Detail
N/A Structure

10312-71-7

N/A

Anisole Structure

100-66-3

Anisole

~%

4-Chloro-4'-methoxy-1,1'-biphenyl Structure

58970-19-7

4-Chloro-4'-met...

1-chloro-4-(3-methoxyphenyl)benzene Structure

66175-36-8

1-chloro-4-(3-m...

Detail
N/A Structure

10312-71-7

N/A

Anisole Structure

100-66-3

Anisole

~%

4-Chloro-4'-methoxy-1,1'-biphenyl Structure

58970-19-7

4-Chloro-4'-met...

1-chloro-4-(3-methoxyphenyl)benzene Structure

66175-36-8

1-chloro-4-(3-m...

Detail
N/A Structure

10312-71-7

N/A

Anisole Structure

100-66-3

Anisole

~%

4-Chloro-4'-methoxy-1,1'-biphenyl Structure

58970-19-7

4-Chloro-4'-met...

1-chloro-4-(3-methoxyphenyl)benzene Structure

66175-36-8

1-chloro-4-(3-m...

Detail
Bromobenzene Structure

108-86-1

Bromobenzene

N/A Structure

10312-71-7

N/A

~%

N'-Acetylacetohydrazide Structure

3148-73-0

N'-Acetylacetoh...

4-Bromo-4'-chlorobiphenyl Structure

23055-77-8

4-Bromo-4'-chlo...

Detail
Bromobenzene Structure

108-86-1

Bromobenzene

1,6-di-p-bromophenyl-3,4-diacetyl-1,5-hexazadiene Structure

79991-24-5

1,6-di-p-bromop...

~%

4,4'-Dibromobiphenyl Structure

92-86-4

4,4'-Dibromobiphenyl

2,4-Dibromo-1,1-Biphenyl Structure

49602-91-7

2,4-Dibromo-1,1...

Detail
N/A Structure

10312-71-7

N/A

Toluene Structure

108-88-3

Toluene

~%

4-CHLORO-4?-METHYLBIPHENYL Structure

19482-11-2

4-CHLORO-4?-MET...

1-chloro-4-(2-methylphenyl)benzene Structure

89346-57-6

1-chloro-4-(2-m...

Detail
Bromobenzene Structure

108-86-1

Bromobenzene

1,6-di-p-bromophenyl-3,4-diacetyl-1,5-hexazadiene Structure

79991-24-5

1,6-di-p-bromop...

~%

4,4'-Dibromobiphenyl Structure

92-86-4

4,4'-Dibromobiphenyl

2,4-Dibromo-1,1-Biphenyl Structure

49602-91-7

2,4-Dibromo-1,1...

Detail
N/A Structure

10312-71-7

N/A

Chlorobenzene Structure

108-90-7

Chlorobenzene

~%

N'-Acetylacetohydrazide Structure

3148-73-0

N'-Acetylacetoh...

2,4'-PCB Structure

34883-43-7

2,4'-PCB

Detail
1-p-chlorophenyl-3,4-diacetyl-1-tetrazene Structure

79991-27-8

1-p-chloropheny...

Chlorobenzene Structure

108-90-7

Chlorobenzene

~%

N'-Acetylacetohydrazide Structure

3148-73-0

N'-Acetylacetoh...

2,4'-PCB Structure

34883-43-7

2,4'-PCB

Detail
N/A Structure

10312-71-7

N/A

Chlorobenzene Structure

108-90-7

Chlorobenzene

Isopropanol Structure

67-63-0

Isopropanol

~%

dimethyl ether Structure

115-10-6

dimethyl ether

Detail

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