Organic letters

An amphiphilic resin-supported palladium catalyst for high-throughput cross-coupling in water

Y Uozumi, Y Nakai

文献索引：Uozumi, Yasuhiro; Nakai, Yasushi Organic Letters, 2002 , vol. 4, # 17 p. 2997 - 3000

被引用次数: 191

摘要

The Suzuki-Miyaura coupling of aryl halides (8 varieties) and aryl-or vinylboronic acids (12 varieties) took place in water in the presence of a palladium complex of an amphiphilic polystyrene-poly (ethylene glycol) copolymer resin-supported N-anchored 2-aza-1, 3-bis (diphenylphosphino) propane ligand and potassium carbonate to give uniform and quantitative yields of the corresponding biaryls (96 varieties).

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