Tetrahedron Letters

Preparation of enantioenriched tetraols and triolamines from a common epoxide

M Kaviani-Joupari, MP Schramm

文献索引：Kaviani-Joupari, Makan; Schramm, Michael P. Tetrahedron Letters, 2013 , vol. 54, # 37 p. 5014 - 5017

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摘要

Abstract We identify a silylcyclopentene oxide that is amenable to several distinct asymmetric catalytic transformations providing access to enantio-enriched tetraol and triol- amines. The sequence employed allows for selective protection of one amine or alcohol from the four heteroatoms that are introduced into the carbon scaffold.