Iron??Catalyzed Cross??Coupling of Alkyl Halides with Alkenyl Grignard Reagents

A Guérinot, S Reymond, J Cossy

文献索引：Guerinot, Amandine; Reymond, Sebastien; Cossy, Janine Angewandte Chemie - International Edition, 2007 , vol. 46, # 34 p. 6521 - 6524

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被引用次数: 114

摘要

Transition-metal-catalyzed CÀC bond coupling between vinyl metal reagents and unactivated alkyl halides is a useful reaction [1–3] that can be realized using copper,[4] palladium, nickel, or cobalt complexes as catalysts.[1–3, 5] For example, primary alkyl bromides can be coupled with alkenyl tin reagents using a palladium-catalyzed Stille coupling.[6] Negishi cross-coupling reactions of alkyl halides with alkenyl zinc reagents [7] ...