Bulletin of the Chemical Society of Japan

The Hydroxyphenylation of Methylstyrenes with Phenylpalladium Chloride

H Horino, N Inoue

文献索引：Horino,H.; Inoue,N. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 2898 - 2901

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被引用次数: 5

摘要

The reaction of α-or β-methylstyrene with phenylpalladium chloride in aqueous acetone were studied. From cis-or trans-β-methylstyrene, a mixture of erythro and threo isomers of hydroxyphenylation products PhMeCHCHOHPh (VIa, VIb) and chlorophenylation products PhMeCHCHClPh (IVa, IVb) were obtained accompanying the phenylated olefins (I, II, and III). The main reaction product was the tertiary alcohol PhCH 2 C (OH) MePh (V). The ...