A Mild Oxidative Aryl Radical Addition into Alkenes by Aerobic Oxidation of Arylhydrazines

T Taniguchi, H Zaimoku…

文献索引：Taniguchi, Tsuyoshi; Zaimoku, Hisaaki; Ishibashi, Hiroyuki Chemistry - A European Journal, 2011 , vol. 17, # 15 p. 4307 - 4312

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被引用次数: 55

摘要

Abstract A mild and practical oxyarylation of alkenes by oxidative radical addition has been developed by using aerobic oxidation of hydrazine compounds. The use of a catalytic amount of potassium ferrocyanide trihydrate (K 4 [Fe (CN) 6]⋅ 3 H 2 O) and water accelerated this radical reaction to give peroxides or alcohols from simple alkenes in good yields. The environmentally friendly and economical radical reactions were achieved at ...