Tetrahedron Letters

A highly efficient method for the hydroaminomethylation of long-chain alkenes under aqueous, biphasic conditions

A Behr, M Becker, S Reyer

文献索引：Behr, Arno; Becker, Marc; Reyer, Sebastian Tetrahedron Letters, 2010 , vol. 51, # 18 p. 2438 - 2441

全文：HTML全文

被引用次数: 17

摘要

The use of salts of secondary and primary amines with different inorganic and organic acids in hydroaminomethylation enables the quantitative conversion of 1-octene with high selectivity for saturated amines. We propose that a cationic rhodium species is formed under the acidic conditions which catalyses the hydrogenation of the enamine or imine formed subsequently. Thus the use of acids and amine salts enables the hydroaminomethylation ...