The Electrolytic Reduction of p-Substituted α-(Methylsulfinyl)-α-(methylthio) acetophenones in Acetonitrile

A Kunugi, N Takahashi, K Abe, T Hirai

文献索引：Kunugi, Akira; Takahashi, Norimasa; Abe, Kyo; Hirai, Taketsugu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 6 p. 2055 - 2057

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被引用次数: 3

摘要

p-Substituted α-(methylsulfinyl)-α-(methylthio) acetophenones (1) exhibit, on polarographic reduction, three waves. The two last waves correspond to the reductions of p-substituted α- (methylthio) acetophenones (2) and p-substituted acetophenones respectively. The macroelectrolysis at the first wave potential results in the formation of 2 in good yields in the presence of benzoic acid. The electrolytic reduction of 1 is characterized by the ...