Hydroaminomethylation with Novel Rhodium–Carbene complexes: An Efficient Catalytic Approach to Pharmaceuticals

…, R Jackstell, H Klein, A Spannenberg…

文献索引：Ahmed, Moballigh; Buch, Cathleen; Routaboul, Lucie; Jackstell, Ralf; Klein, Holger; Spannenberg, Anke; Beller, Matthias Chemistry - A European Journal, 2007 , vol. 13, # 5 p. 1594 - 1601

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被引用次数: 54

摘要

Abstract Starting from [{Rh (cod) Cl} 2] and 1, 3-dimesitylimidazole-2-ylidenes the novel [RhCl (cod)(carbene)] complexes 1–5 have been synthesized, characterized, and tested in the hydroaminomethylation of aromatic olefins. The influence of different ligands and reaction parameters on the catalytic activity was investigated in detail applying 1, 1- diphenylethylene and piperidine as a model system. The scope and limitations of the ...