Journal of organometallic chemistry

Palladium-catalyzed rearrangement of silanes containing oxygen or halogen α to silicon

V Gevorgyan, L Borisova, E Lukevies

文献索引：Gevorgyan, Vladimir; Borisova, Larisa; Lukevics, Edmunds Journal of Organometallic Chemistry, 1992 , vol. 436, # 3 p. 277 - 285

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被引用次数: 5

摘要

Abstract Rearrangements of tetrahydrofuryl-and tetrahydropyranyl-hydrosilanes to oxasilaalkanes, of acetoxymethyl-hydrosilanes to acetoxysilanes, and halogenomethyl- hydrosilanes to halogenosilanes in the presence of palladium catalyst have been studied. The reaction has been shown to proceed more rapidly in tetrahydrofuran and hexane than in benzene or acetonitrile. The progressive replacement of the methyl groups on the silicon ...