Chemistry Letters

Chemistry of organosilicon compounds. 281. Photo-induced electron transfer reaction of polysilanes. Intramolecular trapping of a transient silyl radical cation with a …

Y Nakadaira, A Sekiguchi, Y Funada, H Sakurai

文献索引：Nakadaira, Yasuhiro; Sekiguchi, Akira; Funada, Yasuhito; Sakurai, Hideki Chemistry Letters, 1991 , # 2 p. 327 - 330

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被引用次数: 30

摘要

The radical cation, produced in photo-induced electron transfer of polysilanyl alkanols, can be trapped efficiently intramolecularly with the hydroxyl group. The silyl radical generated in the process is trapped by the solvent employed. A good Hammett relationship is observed in aryldisilanylalkanols between the relative reactivities of the Si–Si bond and σ+ constants of the substituent on the aryl group.