Journal of the American Chemical Society

Regiochemistry of alkenylsilyl and alkenyldisilanyl radical cyclizations

TJ Barton, A Revis

文献索引：Barton,T.J.; Revis,A. Journal of the American Chemical Society, 1984 , vol. 106, p. 3802

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被引用次数: 32

摘要

The purpose of the work reported herein was to determine whether the Baldwin-Beckwith rules could be extended to the cyclizations of alkenyl silicon-centered radicals. The question was whether radicals of type 1 would undergo kinetically controlled exo cyclization to afford 2 or thermodynamically controlled endo cyclization to afford 3.