Alkyl nitrite-metal halide deamination reactions. 3. Arylation of olefinic compounds in the deamination of arylamines by alkyl nitrites and copper (II) halides. A …

MP Doyle, B Siegfried, RC Elliott…

文献索引：Doyle,M.P. et al. Journal of Organic Chemistry, 1977 , vol. 42, p. 2431 - 2436

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被引用次数: 65

摘要

Arylation of olefinic substrates occurs when arylamines are treated with alkyl nitrites and copper (I1) halides in acetonitrile or acetone solutions that contain the olefin. The corresponding 8-aryl-a-halo derivatives are formed in high yields by this direct procedure. Results from direct arylation reactions of representative arylamines with acrylonitrile and styrene in the presence of copper (I1) chloride are reported; isolated yields of arylation ...