Synthetic communications

Tetraorganogallate Complexes in Organic Chemistry: Michael Addition to α, β-unsaturated Compounds

Y Han, YZ Huang, L Fang, WT Tao

文献索引：Han, Ying; Huang, Yao-Zeng; Fang, Lei; Tao, Wen-Tian Synthetic Communications, 1999 , vol. 29, # 5 p. 867 - 876

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被引用次数: 5

摘要

Abstract Tetraorganogallate complexes, prepared in situ by addition of an organolithium reagent to a triorganogallium, reacted smoothly with α, β-unsaturated compounds to give Michael addition products in high yields, and mixed gallates display very high chemoselectivity in the transfer of one of their ligands.