Advanced Synthesis & Catalysis

Rhodium??Catalyzed Double 1, 4??Addition of Arylboronic Acids to β??Aryloxyacrylates Involving β??Oxygen Elimination

T Matsuda, S Shiose, Y Suda

文献索引：Matsuda, Takanori; Shiose, Shigeru; Suda, Yuya Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 1923 - 1926

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被引用次数: 9

摘要

The rhodium-catalyzed carbon carbon bond-forming reactions of organoboron compounds have become an indispensable tool in organic syntheses.1 In particular, the rhodium-catalyzed 1,4-addition reactions to electron-deficient alkenes have been extensively studied.2 However, the 1,4-additions to α,β-unsaturated carbonyl compounds with oxygen functionality at the β position have been limited to cyclic substrates.3 Herein, we report a rhodium- ...