Counterattack reagent hexamethyldisilane in the direct conversion of aldehydes, ketones, and allyl alcohols to allyltrimethylsilanes

JR Hwu, LC Lin, BR Liaw

文献索引：Hwu, Jih Ru; Lin, Lung Ching; Liaw, Ben Ruey Journal of the American Chemical Society, 1988 , vol. 110, # 21 p. 7252 - 7254

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被引用次数: 15

摘要

Counterattack reagent'Me3SiSiMe3 can efficiently silylate hydrazines under alkaline conditiom2 We intended to use the counterattack method to prepare another important class of compounds-allyltrimethylsilanes, The allyltrimethylsilane moiety is versatile in organic This moiety possesses umpolung character and is regarded as a synthon for allyl cations and anions. Three new methods reported herein (see Scheme I) involve the use of ...