Australian Journal of Chemistry

Stereochemical studies. IV. The role of carbocations in the oxidation of alkylhydrazines

CD McLean, S Middleton

文献索引：McLean,C.D.; Middleton,S. Australian Journal of Chemistry, 1978 , vol. 31, p. 2659 - 2667

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被引用次数: 1

摘要

Abstract A study of the oxidation of two neopentylhydrazines by iodine in the presence of base has shown that carbocations are only involved to a minor extent as intermediates in alkyl iodide formation, but are likely to be involved to a considerable extent in the formation of alkenes and alcohols. A comparison is made between the course of oxidation of a given alkylhydrazine and deamination of the corresponding amine.