The Journal of Physical Chemistry A

Radical yields in the radiolysis of branched hydrocarbons: Tertiary CH bond rupture in 2, 3-dimethylbutane, 2, 4-dimethylpentane, and 3-ethylpentane

RH Schuler, L Wojnarovits

文献索引：Schuler, Robert H.; Wojnarovits, Laszlo Journal of Physical Chemistry A, 2003 , vol. 107, # 43 p. 9240 - 9247

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被引用次数: 7

摘要

Gel permeation chromatography has been applied to iodine scavenging studies of the distribution of radicals produced in the radiolysis of symmetrically branched hydrocarbons 2, 3-dimethylbutane, 2, 4-dimethylpentane, and 3-ethylpentane. The principal iodides observed are those expected as a result of simple bond rupture. In the case of 2, 3- dimethylbutane all five expected iodides are readily resolvable and it is shown that the ...