[bmim] BF 4/[Cu (Im 12) 2] CuCl 2 as a novel catalytic reaction medium for click cyclization

M Keshavarz, B Karami, AZ Ahmady, A Ghaedi…

文献索引：Keshavarz, Mosadegh; Karami, Bahador; Ahmady, Amanollah Zarei; Ghaedi, Abdolmohammad; Vafaei, Hakimeh Comptes Rendus Chimie, 2014 , vol. 17, # 6 p. 570 - 576

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被引用次数: 3

摘要

Abstract Herein, a new application of an ionic liquid containing copper (I),([Cu (Im 12) 2] CuCl 2), is introduced. This ionic liquid was used as an efficient catalyst for the click cyclization between organic azides and terminal alkynes in various solvents. Then, the mixture of [bmim] BF 4/[Cu (Im 12) 2] CuCl 2 was used as a green catalytic medium for the multicomponent click synthesis of 1, 4-disubstituted-1H-1, 2, 3-triazoles from α-halo ...