Chemical physics letters

Thermochemical study of the liquid phase equilibrium reaction of dihalomethanes by NMR spectroscopy

JZ Dávalos, AF Lago, T Baer

文献索引：Davalos; Lago; Baer, Tomas Chemical Physics Letters, 2005 , vol. 409, # 4-6 p. 230 - 234

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被引用次数: 6

摘要

The liquid phase equilibrium reaction of dihalomethanes (2CH2BrI⇄ CH2Br2+ CH2I2) has been investigated by NMR spectroscopy, as a function of the temperature and initial concentration of the reactants. The equilibrium constants have been experimentally determined for this reaction from the profile of the NMR spectra. Heat capacity measurements were carried out in the temperature range from 293.15 to 353.15 K by ...