High-field NMR determination of magnetic susceptibility tensors and angular correlation factors of halomethanes

AA Bothner-By, J Dadok, PK Mishra…

文献索引：Bothner-By, A. A.; Dadok, J.; Mishra, P. K.; Zijl, P. C. M. Van Journal of the American Chemical Society, 1987 , vol. 109, # 14 p. 4180 - 4184

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被引用次数: 15

摘要

Abstract: Quadrupolar splittings in the high-resolution deuteron spectra of deuterated haloforms (CX32H, X= CI, Br, I) and methylene halides (CXz1H2H) have been measured at 14.35 T (93.5 MHz) and used to determine the anisotropy or asymmetry of their molecular magnetic susceptibility tensors. By combination with the known isotropic susceptibilities, the principal susceptibility tensors have been deduced and decomposed into bond ...