The Journal of Organic Chemistry

Ynamines from 1, 1-difluoro-2-aryl and 2-alkylethylenes

DR Strobach

文献索引：Strobach,D.R. Journal of Organic Chemistry, 1971 , vol. 36, p. 1438 - 1440

全文：HTML全文

被引用次数: 11

摘要

(0.248 mol) of 4-cyclooctenone1B and 73 g (0.27 mol) of methyl- ene iodide was added in one portion. The mixture was refluxed for 2 days, after which glpc analysis of the ether solution indi- cated that the reaction had only gone to a small extent (ca. 30%). Another 18 g of the zinc-copper couple was added to the mixture and this was followed by another 73 g (0.27 mol) of methylene iodide. The mixture was then refluxed for another 2 days. The mixture ...