The Journal of Organic Chemistry

Ynamines from 1, 1-difluoro-2-aryl and 2-alkylethylenes

DR Strobach

Index: Strobach,D.R. Journal of Organic Chemistry, 1971 , vol. 36, p. 1438 - 1440

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Citation Number: 11

Abstract

(0.248 mol) of 4-cyclooctenone1B and 73 g (0.27 mol) of methyl- ene iodide was added in one portion. The mixture was refluxed for 2 days, after which glpc analysis of the ether solution indi- cated that the reaction had only gone to a small extent (ca. 30%). Another 18 g of the zinc-copper couple was added to the mixture and this was followed by another 73 g (0.27 mol) of methylene iodide. The mixture was then refluxed for another 2 days. The mixture ...