Oxidation of isobutene and methylenecycloalkanes by palladium (II) acetate

K Kikukawa, K Sakai, K Asada, T Matsuda

文献索引：Kikukawa,K. et al. Journal of Organometallic Chemistry, 1974 , vol. 77, p. 131 - 145

全文：HTML全文

被引用次数: 17

摘要

Abstract Reactions of isobutene, methylenecyclopentane, methylenecyclohexane and methylenecycloheptane with palladium acetate were studied in acetic acid at 30 to 80. Two types of oxidation were identified: acetoxylation to allylic acetates (methylenecycloheptane) and oxidative coupling to dimers (isobutene and methylenecyclohexane). A mechanistic study indicated that the former was produced by thermal decomposition of the initially ...