European journal of organic chemistry

Asymmetric Dihydroxylation of β, γ??Unsaturated Carboxylic Esterswith Trisubstituted C= C Bonds–Enantioselective Syntheses of Trisubstituted γ??Butyrolactones

T Kapferer, R Brückner

文献索引：Kapferer, Tobias; Brueckner, Reinhard European Journal of Organic Chemistry, 2006 , # 9 p. 2119 - 2133

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被引用次数: 18

摘要

Abstract β, γ-Unsaturated esters with stereodefined trisubstitued C= C double bonds were prepared by the Arndt–Eistert homologation of α, β-unsaturated carboxyl halides, by two- step methoxycarbonylation of allylbarium reagents, by deconjugation of α, β-unsaturated esters, and by Horner–Wadsworth–Emmons variants of the Stobbe condensation. Sharpless asymmetric dihydroxylation of the β, γ-unsaturated esters, followed by spontaneous ...