Amides II. Acylation of amides to diacylimines

JB Polya, TM Spotswood

文献索引：Polya; Spotswood Recueil des Travaux Chimiques des Pays-Bas, 1948 , vol. 67, p. 936

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被引用次数: 19

摘要

Three acylating mechanisms are involved in the reaction between amides and anhydrides. In the aliphatic series all mechanisms are governed by the indilctive effects operating in the reactants. Amides act as acids towards anhydrides. Diacylimines and the corresponding anhydrides acylate alcohols by the same mechanism. A new compound, propionylchloroacetarnide, has been prepared. Pro- perties of some diacylimines have been established. Uses for ...