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Dendrimers as photochemical reaction media. Photochemical behavior of unimolecular and bimolecular reactions in water-soluble dendrimers

…, J Nithyanandhan, N Jayaraman…

文献索引:Kaanumalle, Lakshmi S.; Ramesh; Maddipatla, V. S. N. Murthy; Nithyanandhan, Jayaraj; Jayaraman, Narayanaswamy; Ramamurthy Journal of Organic Chemistry, 2005 , vol. 70, # 13 p. 5062 - 5069

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被引用次数: 43

摘要

Synthesis and studies of poly (alkyl aryl ether) dendrimers, possessing carboxylic acid functionalities at their peripheries, are reported. 5-Bromopentyloxy methylisophthalate was utilized as the monomer to O-alkylate the phenolic hydroxyl groups of poly (alkyl aryl ether) dendrimers. Dendrimers of first, second, and third generations, possessing 6, 12, and 24 carboxylic acids, respectively, were thus prepared. These dendrimers were soluble in ...