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Alkali ion exchanged nafion as a confining medium for photochemical reactions

S Arumugam, LS Kaanumalle…

文献索引:Arumugam, Selvanathan; Kaanumalle, Lakshmi S.; Ramamurthy Photochemistry and Photobiology, 2006 , vol. 82, # 1 p. 139 - 145

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被引用次数: 7

摘要

ABSTRACT Methanol-swollen Nafion beads were used as microreactors to control the photochemical reaction pathways. Product selectivity in three unimolecular reactions, namely, the photo-Fries rearrangement of naphthyl esters, Norrish Type I reaction of 1- phenyl-3-p-tolyl-propan-2-one and Norrish Type I and Type II reactions of benzoin alkyl ethers were examined. The influence of cations over the photodimerization of ...