Dendrimers as photochemical reaction media. Photochemical behavior of unimolecular and bimolecular reactions in water-soluble dendrimers

…, J Nithyanandhan, N Jayaraman…

Index: Kaanumalle, Lakshmi S.; Ramesh; Maddipatla, V. S. N. Murthy; Nithyanandhan, Jayaraj; Jayaraman, Narayanaswamy; Ramamurthy Journal of Organic Chemistry, 2005 , vol. 70, # 13 p. 5062 - 5069

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Citation Number: 43

Abstract

Synthesis and studies of poly (alkyl aryl ether) dendrimers, possessing carboxylic acid functionalities at their peripheries, are reported. 5-Bromopentyloxy methylisophthalate was utilized as the monomer to O-alkylate the phenolic hydroxyl groups of poly (alkyl aryl ether) dendrimers. Dendrimers of first, second, and third generations, possessing 6, 12, and 24 carboxylic acids, respectively, were thus prepared. These dendrimers were soluble in ...