Tetrahedron letters

Ruthenium-catalyzed regioselective α-alkylation of ketones with primary alcohols

CS Cho, BT Kim, TJ Kim, SC Shim

文献索引：Cho, Chan Sik; Kim, Bok Tae; Kim, Tae-Jeong; Chul Shim, Sang Tetrahedron Letters, 2002 , vol. 43, # 44 p. 7987 - 7989

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被引用次数: 130

摘要

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Ketones are regioselectively alkylated with an array of primary alcohols in dioxane at 80°C in the presence of a catalytic amount of a ruthenium catalyst together with KOH and a hydrogen acceptor. ... Ketones react with primary alcohols in the presence of RuCl 2 (PPh 3 ) 3 , KOH and a ...

~80%

~79%

~51%

~48%

~83%

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