Organic & biomolecular chemistry

A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature

M Lamani, P Devadig, KR Prabhu

文献索引：Lamani, Manjunath; Devadig, Pradeep; Prabhu, Kandikere Ramaiah Organic and Biomolecular Chemistry, 2012 , vol. 10, # 14 p. 2753 - 2759

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被引用次数: 22

摘要

A novel non-metal catalyzed oxidation of organic azides to nitriles under solvent-free conditions is presented employing catalytic amounts of KI, and DABCO in aq. TBHP at room temperature. This non-metal catalyzed oxidation of azides provides good selectivity as double and triple bonds were not oxidized under the present reaction conditions.

~90%

~84%

609770-35-6

2-(叠氮基甲基)吡啶

~80%

~85%

~84%

~78%

~82%

~89%

~80%

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