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Tetrahedron

The preparation and chemistry of α-nitroepoxides

H Newman, RB Angier

文献索引:Newman,H.; Angier,R.B. Tetrahedron, 1970 , vol. 26, p. 825 - 836

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被引用次数: 53

摘要

The preparation of α-nitroepoxides from nitro olefins and hydrogen peroxide in the presence of base is reported and the behaviour of this new chemical species towards selected nucleophiles, acids and reducing agents is described. Mass spectral data is also presented. ... ☆ A preliminary account of some aspects of this work has appeared: H. Newman and RB Angier, Chem. Comm. 369 (1969).