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The Journal of Organic Chemistry

Oxidations with Oxygen Difluoride. II. Addition to Unsaturated Carbon

RF Merritt, JK Ruff

文献索引:Merritt,R.F.; Ruff,J.K. Journal of Organic Chemistry, 1965 , vol. 30, p. 328 - 331

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被引用次数: 18

摘要

Following the initial preparation of oxygen difluoride (OF,) by Lebeau and Damiens' in 1927, the investigation of the chemistry of this powerful oxidant was confined to various inorganic systems. However, recent work3 has shown that OF, oxidations of organic substrates can be controlled in the case of primary aliphatic amines. The facile amine oxidationJ3 which was rapid at-78', suggested extension of similar