Radical intermediates in the peroxidation of indoles

P Astolfi, L Greci, C Rizzoli, P Sgarabotto…

文献索引：Astolfi; Greci; Rizzoli; Sgarabotto; Marrosu Journal of the Chemical Society, Perkin Transactions 2, 2001 , # 9 p. 1634 - 1640

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被引用次数: 20

摘要

Results The indoles studied in the present work were 2-alkylindoles (R′= methyl, 5; R′= tert-butyl, 6; R′= phenyl, 7), 1, 2-dialkylindoles (R= R′= methyl, 8; R= ethyl, R′= phenyl, 9)(Scheme 1), 2, 3-dialkylindoles (R= R′= methyl, 14a; R= R′= phenyl 14b; see Scheme 2) and 1-hydroxy-2-phenylindole 16. All indoles were reacted in the presence of oxygen with m-chloroperbenzoic acid and hydrogen peroxide using trichloroacetic acid or calcium ...