Heats of formation of some simple alkyl radicals

AL Castelhano, D Griller

文献索引：Castelhano, A. L.; Griller, D. Journal of the American Chemical Society, 1982 , vol. 104, # 13 p. 3655 - 3659

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被引用次数: 127

摘要

1. Substitution of hydrogen by lithium in the methyl cation lowers the energy of triplet states more than singlets. CH2Li+ is still a ground-state singlet, but with a much reduced singlettriplet separation compared with CH3+. CHLi2+ and CLi3+ are predicted to have triplet ground states. 2. The ionization potential of CLi, is predicted to be 6 eV less than that of CH3, in reasonable agreement with experiment. 3. Lithium is a strong stabilizing ...