Journal of the American Chemical Society

Studies of free radicals at high pressures. 2. Kinetics for a variety of reactions

PR Marriott, D Griller

文献索引：Marriott, P. R.; Griller, D. Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1521 - 1525

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被引用次数: 16

摘要

Abstract: Kinetic EPR studies of a variety of free-radical reactions have been carried out at high pressures. Volumes of activation were measured for the@-scission reactions of di-tert- butyliminyl (3.0 i 1. O cm3 mol-') and triethoxy-tert-butoxyphosphoranyl (0.2 f 1.9 cm3 mol-I), for the self-reaction of di-tert-butyliminyl (-18.0 i 5.3 cm3 mol-I), and for the rearrangements of 2, 4, 6-tri-tert-butylphenyl (5.3 i 1.7 cm3 mol-') and 2, 4, 6-tris (perdeuterio-tert-butyl) ...