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The Journal of Organic Chemistry

Reaction of 1-bromomethylene-2, 2-dimethylcyclobutane with potassium tert-butoxide

KL Erickson

文献索引:Erickson,K.L. Journal of Organic Chemistry, 1971 , vol. 36, # 8 p. 1031 - 1036

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被引用次数: 9

摘要

In an effort to learn more about the mechanism of this unusual type of transformation, an unsymmetrically substituted m~ ethylenecyclobutane, l-bromomethylene-2, 2- dimethylcyclobutane (1), has been synthesized and subjected to the reaction conditions. The results of this study, reported herein, provide some insight into the nature of this rearrangement reaction.