Tetrahedron

Transposition homoallenylique—VIII: Solvolyse de tosylates β alleniques acycliques identification des produits

M Santelli, M Bertrand

文献索引：Santelli,M.; Bertrand,M. Tetrahedron, 1974 , vol. 30, p. 227 - 233

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被引用次数: 11

摘要

Solvolysis of acyclic allenic tosylates shows that the allene group participates strongly to give cyclopropyl ketones and methylenecyclobutanols. Whenever C4 and C5 of the 3-methyl penta-1, 2 dien-5-yl system carry different substituents, an apparent exchange of position between them occurs during the cyclisation.