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Tetrahedron

Cyclopropanones—VIII: Preparation and characterization of cyclopropanone, methylcyclopropanone, 2, 2-dimethylcyclopropanone and tetramethylcyclopropanone

NJ Turro, WB Hammond

文献索引:Turro,N.J.; Hammond,W.B. Tetrahedron, 1968 , vol. 24, p. 6017 - 6028

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被引用次数: 31

摘要

The preparations of cyclopropanone (1), methylcyclopropanone (2), 2, 2- dimethylcyclopropane (3) and tetramethylcyclopropane (4), are described. The spectral properties of these molecules demonstrate unambiguously the ring closed structure for cyclopropanones. The reactions of cyclopropanones with methanol, diazomethane and furan are employed as chemical means of characterization.