From diols to lactones under aerobic conditions using a laccase/TEMPO catalytic system in aqueous medium

A Díaz??Rodríguez, I Lavandera…

文献索引：Gotor-Fernandez, Vicente; Diaz-Rodriguez, Alba; Lavandera, Ivan; Kanbak-Aksu, Seda; Sheldon, Roger A.; Gotor, Vicente Advanced Synthesis and Catalysis, 2012 , vol. 354, # 18 p. 3405 - 3408

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被引用次数: 24

摘要

Abstract An efficient catalytic system to oxidize quantitatively aliphatic diols using Trametes versicolor laccase and TEMPO has been developed in aqueous medium. Oxidations have occurred in a non-stereoselective fashion but with complete regio-and/or monoselectivity, obtaining lactones with excellent purity after simple extraction. This catalytic system has been demonstrated to be scalable, compatible with the presence of a variety of ...