Diastereoselective Remote C H Activation by Hydroboration

…, B Goldfuss, D Denisenko, J Kulhanek…

文献索引：Varela, Jesus A.; Pena, Diego; Goldfuss, Bernd; Denisenko, Dmitri; Kulhanek, Jiri; Polborn, Kurt; Knochel, Paul Chemistry - A European Journal, 2004 , vol. 10, # 17 p. 4252 - 4264

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被引用次数: 23

摘要

Abstract Hydroboration of tetrasubstituted or trisubstituted alkenes with BH 3 and subsequent thermolysis allows remote diastereoselective C [BOND] H activation of neighboring aryl rings. Tetrasubstituted and trisubstituted 1, 1-diphenylethylene derivatives undergo a highly stereoselective 1, 2-rearrangement followed by remote C [BOND] H activation to lead, after oxidative workup, to a diol in which the relative stereochemistry of ...