Preparation of Thiol Acids, Thiol Esters and Amides by Reactions of Carbonyl Sulfide with Grignard Reagents

AR Katritzky, JL Moutou, Z Yang

文献索引：Katritzky, Alan R.; Moutou, Jean-Luc; Yang, Zhijun Organic Preparations and Procedures International, 1995 , vol. 27, # 3 p. 361 - 366

全文：HTML全文

被引用次数: 2

摘要

Reactions of Grignard reagents with carbon dioxide are well documented in the literature, and provide a general method for the preparation of carboxylic acids. 1.2 Similarly, dithiocarboxylic acids and esters have been prepared from carbon disulfide. 3 Grignard reagents were reported to react with carbonyl sulfide affording mixtures of thiol acids (9- 73%) and tertiary alcohols (22-52%) in ratios which depend on the Grignard reagent used! ...