Acylation of cyclooctatetraene dianion and the chemistry of its products

TS Cantrell, H Shechter

文献索引：Cantrell,T.S.; Shechter,H. Journal of the American Chemical Society, 1967 , vol. 89, p. 5868 - 5876

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被引用次数: 26

摘要

5868 dried over magnesium sulfate. Preparative glpc (20 ft X ... 20% silicone nitrile on Chromosorb P, 60-80 mesh; isothermal at 150') was used to collect the remaining product. Its infrared and nmr spectra were superimposable on those of an authentic sample of 13 prepared by an independent synthesis described below. Preparation of Cyclohex-3-en-1-yltrimethyltin (13). To 0.43 g (17 g-atoms) of magnesium turnings in 50 ml of anhydrous ether was added, dropwise, over a ...