Journal of organometallic chemistry

Substitutions catalysees au nickel d'acetates et de sulfones allyliques

T Cuvigny, M Julia

文献索引：Cuvigny, Therese; Julia, Marc Journal of Organometallic Chemistry, 1986 , vol. 317, p. 383 - 408

被引用次数: 31

摘要

Abstract The allylic substitution of stable enolates derived from diethyl malonate, ethyl cyanoacetate, ethyl benzylsulfonylacetate, bis (benzenesulfonyl) methane and sodium p- toluenesulfinate by a variety of allylic esters and sulfones have been investigated. Suitable ligands and reaction conditions have been found to ensure high yields, and in some cases considerable control of the regioselectivity of the reaction.

820-71-3

甲基丙烯醇乙酸酯

~97%

~20%

~48%

~30%

~94%

~31%

~36%

详细

~82%

~70%

~74%

~72%

~80%

~53%

~69%

~18%

详细

~69%

~29%

详细

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