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Constituents of pyrethrum flowers. XXIII. Cinerolone and the synthesis of related cyclopentenolones

MS Schechter, N Green…

文献索引:Schechter; Green; La Forge Journal of the American Chemical Society, 1949 , vol. 71, p. 3168

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被引用次数: 142

摘要

Summary The acrylic esters of eight alcohols containing tertiary amino groups were prepared by the alcoholysis of methyl or ethyl acrylate. All attempts to polymerize the esters with benzoyl peroxide, ammonium persulfate or heat, whether in bulk, in solution or in aqueous emulsion, were failures. Ultraviolet light was effective in promoting polymerization.