Dimethylglyoxime
Names
[ CAS No. ]:
95-45-4
[ Name ]:
Dimethylglyoxime
[Synonym ]:
Diactyldioxime
2,3-butane-dione dioxime
DIACETYLDIOXIME
EINECS 202-420-1
dimethyl-glyoxim
butane-2,3-dione dioxime
biacetyldioxime
Butane dioxime
1,2-dimethylglyoxyl dioxime
(CH3)2C2(NOH)2
ETCHANT INDICATOR
MFCD00002117
METHYL GLOXIME
Biological Activity
[Description]:
[Related Catalog]:
Chemical & Physical Properties
[ Density]:
0.8
[ Boiling Point ]:
271.529ºC at 760 mmHg
[ Melting Point ]:
240-241 °C(lit.)
[ Molecular Formula ]:
C4H8N2O2
[ Molecular Weight ]:
116.11900
[ Flash Point ]:
14ºC
[ Exact Mass ]:
116.05900
[ PSA ]:
65.18000
[ LogP ]:
0.68660
[ Index of Refraction ]:
1.487
[ Storage condition ]:
2-8°C
[ Stability ]:
Stable. Incompatible with strong oxidizing agents.
[ Water Solubility ]:
INSOLUBLE
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EK2975000
- CHEMICAL NAME :
- 2,3-Butanedione, dioxime
- CAS REGISTRY NUMBER :
- 95-45-4
- BEILSTEIN REFERENCE NO. :
- 0506731
- LAST UPDATED :
- 199709
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C4-H8-N2-O2
- MOLECULAR WEIGHT :
- 116.14
- WISWESSER LINE NOTATION :
- QNUY1&Y1&UNQ
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 250 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Morphological transformation
- TEST SYSTEM :
- Rodent - hamster Embryo
- DOSE/DURATION :
- 100 ug/L
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 18,289,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81812 No. of Facilities: 31 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 83 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81812 No. of Facilities: 143 (estimated) No. of Industries: 6 No. of Occupations: 4 No. of Employees: 480 (estimated) No. of Female Employees: 80 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H301
[ Precautionary Statements ]:
P210-P301 + P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22
[ Safety Phrases ]:
S22-S24/25
[ RIDADR ]:
UN 2926 4.1/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
EK2975000
[ Hazard Class ]:
3.0
[ HS Code ]:
29280090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2928000090
[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
Lab Chip 15 , 2808-18, (2015)
Exposure to metal-containing aerosols has been linked with adverse health outcomes for almost every organ in the human body. Commercially available techniques for quantifying particulate metals are ti...
Nickel on the Dutch market: 10 years after entry into force of the EU Nickel Directive.Contact Dermatitis 65(2) , 115-7, (2011)
Nickel and platinum group metal nanoparticle production by Desulfovibrio alaskensis G20.
New Biotechnology 32 , 727-31, (2015)
Desulfovibrio alaskensis G20 is an anaerobic sulfate reducing bacteria. While Desulfovibrio species have previously been shown to reduce palladium and platinum to the zero-state, forming nanoparticles...