2-Furaldehyde diethyl acetal
Names
[ CAS No. ]:
13529-27-6
[ Name ]:
2-Furaldehyde diethyl acetal
[Synonym ]:
EINECS 236-872-6
2-Furaldehyde Diethyl Acetal
Furfural Diethyl Acetal
MFCD00003245
Chemical & Physical Properties
[ Density]:
1.008 g/mL at 25 °C(lit.)
[ Boiling Point ]:
189-191 °C(lit.)
[ Molecular Formula ]:
C9H14O3
[ Molecular Weight ]:
170.20600
[ Flash Point ]:
148 °F
[ Exact Mass ]:
170.09400
[ PSA ]:
31.60000
[ LogP ]:
2.35120
[ Vapour Pressure ]:
0.713mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.444(lit.)
[ Storage condition ]:
0-6°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36-S24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2932190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2932190090
[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
J. Org. Chem. 50(25) , 5215-22, (1985)
Synthesis of 5-pyridyl-2-furaldehydes via palladium-catalyzed cross-coupling with triorganozincates.
Org. Lett. 4(3) , 375-8, (2002)
5-Pyridyl- and 5-aryl-2-furaldehydes are prepared from furaldehyde diethyl acetal in a four-step, one-pot procedure:(i) deprotonation; (2) Li to Zn transmetalation; (3) Pd-mediated cross-coupling; (4)...