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亚氨基二乙酸

亚氨基二乙酸用途

亚氨基二乙酸(IDA)是一种强结合过渡金属的螯合剂[1]。亚氨基二乙酸可用于去除水中的有毒金属离子。亚氨基二乙酸可以作为一种生物标记物,潜在地预测ARDS(急性呼吸窘迫综合征)的严重程度。

亚氨基二乙酸名称

[ CAS 号 ]:
142-73-4

[ 中文名 ]:
亚氨基二乙酸

[ 英文名 ]:
Iminodiacetic acid

[中文别名 ]:

[英文别名 ]:

2-(carboxymethylamino)acetic acid
Iminodiacetic acid
N-(carboxymethyl)- glycine
MFCD00004280
diglycine
IDA
EINECS 205-555-4
Glycine, N-(carboxymethyl)-
2,2'-Azanediyldiacetic acid
2,2'-Iminodiacetic acid

亚氨基二乙酸生物活性

[ 描述 ]:

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. M D Loberg, et al. Development of new radiopharmaceuticals based on N-substitution of iminodiacetic acid. J Nucl Med. 1976 Jul;17(7):633-8.

[2]. Misra RK, et al. Iminodiacetic acid functionalized cation exchange resin for adsorptive removal of Cr(VI), Cd(II), Ni(II) and Pb(II) from their aqueous solutions. J Hazard Mater. 2011 Jan 30;185(2-3):1508-12.

[3]. Shihui Lin, et al. Explore potential plasma biomarkers of acute respiratory distress syndrome (ARDS) using GC-MS metabolomics analysis. Clin Biochem. 2019 Apr;66:49-56.

亚氨基二乙酸物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
370.6±27.0 °C at 760 mmHg

[ 熔点 ]:
243 °C (dec.)(lit.)

[ 分子式 ]:
C₄H₇NO₄

[ 分子量 ]:
133.10

[ 闪点 ]:
177.9±23.7 °C

[ 精确质量 ]:
133.037506

[ PSA ]:
86.63000

[ LogP ]:
-1.40

[ 外观性状 ]:
白色晶体

[ 蒸汽压 ]:
0.0±1.8 mmHg at 25°C

[ 折射率 ]:
1.501

[ 储存条件 ]:
室温

[ 水溶解性 ]:
2.43 g/100 mL (5 ºC)

亚氨基二乙酸MSDS

亚氨基二乙酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AI2975000

CHEMICAL NAME :: Acetic acid, iminodi-

CAS REGISTRY NUMBER :: 142-73-4

BEILSTEIN REFERENCE NO. :: 0878499

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C4-H7-N-O4

MOLECULAR WEIGHT :: 133.12

WISWESSER LINE NOTATION :: QV1M1VQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4728 No. of Facilities: 25 (estimated) No. of Industries: 4 No. of Occupations: 5 No. of Employees: 293 (estimated) No. of Female Employees: 43 (estimated)

亚氨基二乙酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
AI2975000

[ 海关编码 ]:
29224995

亚氨基二乙酸合成路线

亚氨基二乙酸上下游产品

亚氨基二乙酸上游产品

亚氨基二乙酸下游产品

亚氨基二乙酸制备

１．氯乙酸钠法　由氯乙酸制备氯乙酸钠，再与水合肼反应生成肼抱二乙酸，最后在亚硝酸钠作用下制得亚氨基乙酸。

　２．氯乙酸和氨基乙酸法

　３．氨基乙酸和乙醇腈法

亚氨基二乙酸海关

[ 海关编码 ]: 2922499990

[ 中文概述 ]:
2922499990 其他氨基酸及其酯及它们的盐（含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: P.进境动植物、动植物产品检疫 Q.出境动植物、动植物产品检疫 R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

亚氨基二乙酸文献

Selective Solid-Phase Extraction of Zinc(II) from Environmental Water Samples Using Ion Imprinted Activated Carbon.

J. AOAC Int. 98(1) , 206-12, (2015)

A simple ion imprinted amino-functionalized sorbent was synthesized by coupling activated carbon with iminodiacetic acid, a functional compound for metal chelating, through cyanoric chloride spacer. T...

Quantitative structure-activity relationship and complex network approach to monoamine oxidase A and B inhibitors.

J. Med. Chem. 51 , 6740-51, (2008)

The work provides a new model for the prediction of the MAO-A and -B inhibitor activity by the use of combined complex networks and QSAR methodologies. On the basis of the obtained model, we prepared ...

Immobilized metal affinity chromatography using open tubular capillary for phosphoprotein analysis: comparison between polymer brush coating and surface functionalization.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 879(27) , 2852-9, (2011)

In the present article, open tubular-IMAC columns, functionalized by iminodiacetic acid (IDA) for the immobilization of Fe(3+), were prepared by in situ chemical modification of fused silica capillary...

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