dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii) structure
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Common Name | dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii) | ||
|---|---|---|---|---|
| CAS Number | 905459-27-0 | Molecular Weight | 681.475 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C32H42Cl3N3Pd | Melting Point | 240℃ (DEC.) | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | [1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride |
|---|---|
| Synonym | More Synonyms |
| Melting Point | 240℃ (DEC.) |
|---|---|
| Molecular Formula | C32H42Cl3N3Pd |
| Molecular Weight | 681.475 |
| Exact Mass | 679.147888 |
| PSA | 19.37000 |
| LogP | 3.80850 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302-H312-H332 |
| Precautionary Statements | P280 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xn |
| Risk Phrases | 20/21/22 |
| RIDADR | NONH for all modes of transport |
| HS Code | 28439000 |
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A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.
Chemistry 12 , 4749, (2006) We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ... |
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Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.
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Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.
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| 1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole,3-chloropyridine,dichloropalladium |